- Protonation of diarylacetylenes in superacid HSO3F and their oxidation in the HSO3F/PbO2 system: one-pot synthesis of polysubstituted naphthalenes.
[作者:Vasilyev, Aleksander V.;Shchukin, Andrey O.;Walspurger, Stephane;Sommer, Jean;,期刊:European Journal of Organic Chemistry, 页码:4632-4639 , 文章类型: 研究论文,,卷期:2008年-27]
- In the superacid HSO3F, diarylacetylenes bearing one electron-withdrawing group (NO2, CN, COMe, CO2Me) in each arene ring form stable ions, protonated at these groups. Oxidn. of such diarylacetylenes in the HSO3F/PbO2 s...
- Cyano-, nitro- and nitrosomethane derivatives: structures and gas-phase acidities.
[作者:Brand, Harald;Liebman, Joel F.;Schulz, Axel;,期刊:European Journal of Organic Chemistry, 页码:4665-4675 , 文章类型: 研究论文,,卷期:2008年-27]
- The structures and gas-phase acidities of resonance-stabilized methane/methanide derivs. (H[CR1R2R3]/[CR1R2R3]- with R1,2,3 = H, NO2, NO, and CN) have been studied through B3LYP/aug-cc-pvTZ computations. The gas-phase a...
- Biphenyl-based disc- vs. rod-shaped phenylacetylenes: mesomorphism and electronic properties.
[作者:Hennrich, Gunther;Ortiz, Pedro D.;Cavero, Emma;Hanes, Robert, E.;Serrano, Jose Luis;,期刊:European Journal of Organic Chemistry, 页码:4575-4579 , 文章类型: 研究论文,,卷期:2008年-27]
- A std. Sonogashira coupling protocol has been applied for the prepn. of a C3-sym. phenylacetylene (2) and the corresponding linear phenylacetylene (3) incorporating terminal biphenyl substituents. The study of the mesom...
- A simple two-step sequence for the synthesis of novel 4-aryl-4,5-dihydro-6H-[1,3]dioxolo[4,5-h]pyrrolo[1,2-a][1]benzazepin-6-o nes from 6-amino-3,4-methylenedioxyacetophenone.
[作者:Abonia, Rodrigo;Cuervo, Paola;Insuasty, Braulio;Quiroga, Jairo;Nogueras, Manuel;Cobo, Justo;,期刊:European Journal of Organic Chemistry, 页码:4684-4689 , 文章类型: 研究论文,,卷期:2008年-27]
- Here is provided an efficient and two-step short procedure for the synthesis of novel 6H-[1,3]dioxolobenzo[4,5-h]pyrrolo[1,2-a][1]benzazepin-6-one derivs., e.g., I, promoted by com. phosphoric acid. In a parallel approa...
- 1-Oxoniaadamantane.
[作者:Etzkorn, Markus;Aniszfeld, Robert;Li, Tiejun;Buchholz, Herwig;Rasul, Golam;Prakash, G. K. Surya;Olah, George A.;,期刊:European Journal of Organic Chemistry, 页码:4555-4558 , 文章类型: 研究论文,,卷期:2008年-27]
- The missing member of the heteroadamantane series, 1-oxoniaadamantane (I), was prepd. by the ionization of suitable bicyclic precursors under strongly acidic conditions. The ion I was characterized by 1H and 13C NMR spe...
- Synthesis of alkaloids of Galipea officinalis by alkylation of an a-amino nitrile.
[作者:Shahane, Saurabh;Louafi, Fadila;Moreau, Julie;Hurvois, Jean-Pierre;Renaud, Jean-Luc;van de Weghe, Pierre;Roisnel, Thierry;,期刊:European Journal of Organic Chemistry, 页码:4622-4631 , 文章类型: 研究论文,,卷期:2008年-27]
- A new synthetic approach directed towards the synthesis of naturally occurring 2-alkyl-tetrahydroquinolines was described. The C-C bonds in the a position relative to the nitrogen atom were formed by the reversal of the...
- Protection/deprotection-free syntheses and structural analysis of (keto-aryl)diynes.
[作者:Osowska, Karolina;Lis, Tadeusz;Szafert, Slawomir;,期刊:European Journal of Organic Chemistry, 页码:4598-4606 , 文章类型: 研究论文,,卷期:2008年-27]
- The reactions of 4-BrC6H4COR [R = H, Me, Et, Ph] with Me3SiCYCH (Sonogashira coupling) followed by in situ deprotection and subsequent dimerization gave thermally stable dimeric keto diynes 4-RCOCYCCYCCYCCOR-4 (I) as yel...
- Pd(OAc)2/p-benzoquinone-catalyzed anaerobic electrooxidative homocoupling of arylboronic acids, arylboronates and aryltrifluoroborates in DMF and/or water.
[作者:Amatore, Christian;Cammoun, Chama;Jutand, Anny;,期刊:European Journal of Organic Chemistry, 页码:4567-4570 , 文章类型: 研究论文,,卷期:2008年-27]
- A new anaerobic electrooxidative homocoupling of arylboronic acids, arylboronates and aryltrifluoroborates was developed in the presence of catalytic amts. of Pd(OAc)2 and p-benzoquinone, which serves as a redox mediator...
- InCl3-catalyzed rapid 1,3-alkoxy migration in glycal ethers: stereoselective- synthesis of unsaturated a-O-glycosides and an a,a-(1?)-linked disaccharide.
[作者:Nagaraj, Paramathevar;Ramehs, Namakkal G.;,期刊:European Journal of Organic Chemistry, 页码:4607-4614 , 文章类型: 研究论文,,卷期:2008年-27]
- InCl3 catalyzes a facile stereoselective 1,3-migration of allylic ethers of glycals to afford 2-C-methylene- and 2,3-unsatd.-a-O-glycosides in high yields. The reaction is rapid (10 min), requires only 20 mol-% of the c...
- Improved preparation of 4,6,6-trimethyl-1,3,2-dioxaborinane and its use in a simple [PdCl2(TPP)2]-catalyzed borylation of aryl bromides and iodides.
[作者:PraveenGanesh, Nageswaran;Chavant, Pierre Yves;,期刊:European Journal of Organic Chemistry, 页码:4690-4696 , 文章类型: 研究论文,,卷期:2008年-27]
- A convenient prepn. of 4,6,6-trimethyl-1,3,2-dioxaborinane (MethylPentaneDiolBorane, MPBH) and its use in the [PdCl2(PPh3)2]-catalyzed borylation of aryl bromides and iodides is reported. The boronic esters undergo rapi...
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