- Effects on the reactivity by changing the electrophilic center from C=O to C=S: contrasting reactivity of hydroxide, p-chlorophenoxide, and butan-2,3-dione monoximate in DMSO/H2O mixtures.
[作者:Um, Ik-Hwan;Han, Jeong-Yoon;Buncel, Erwin;,期刊:Chemistry-A European Journal, 页码:1011-1017 , 文章类型: 研究论文,,卷期:2009年15-4]
- Second-order rate consts. have been measured spectrophotometrically for the reactions of O-p-nitrophenyl thionobenzoate (1, PNPTB) with HO-, butan-2,3-dione monoximate (Ox-, a-nucleophile), and p-chlorophenoxide (p-ClPhO...
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