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  • Thioimidate N-Oxides: From Nature to Synthetic Pathways
    [作者:SCHLEISS JULIE; CERNIAUSKAITE DEIMANTE; GUEYRARD DAVID; IORI RENATO; ROLLIN PATRICK; TATIBOUET ARNAUD,期刊:SYNLETT, 页码:725-728 , 文章类型: Article,,卷期:2010年-5]
  • Inspired by the unexpected reactivity of desulfated naturally occurring glucoraphenin, methods to synthesize thioimidate N-oxides (TIO) have been devised on simple or carbohydrate templates. Either through halocyclizatio...
  • Synthesis of (+)-Kuraramine
    [作者:FRIGERIO FABIO; HASELER CLAIRE A; GALLAGHER TIMOTHY,期刊:SYNLETT, 页码:729-730 , 文章类型: Article,,卷期:2010年-5]
  • The first synthesis of (+)-kuraramine via oxidative cleavage of (-)-N-methylcytisine is reported. An alternative but unsuccessful approach to (+)-kuraramine is also described based on extending an intramolecular enolate ...
  • K-10-Catalyzed Highly Diastereoselective Synthesis of Aziridines
    [作者:BORKIN DMITRY; CARLSON ALENA; TOROK BELA,期刊:SYNLETT, 页码:745-748 , 文章类型: Article,,卷期:2010年-5]
  • A new solid acid-catalyzed method was developed for the stereoselective preparation of cis-aziridines from imines and ethyl diazoacetate using montmorillonite K-10 as catalyst. The reactions proceeded readily at room tem...
  • A Simple Route Toward New Clomiphene Metabolites
    [作者:VITORIANO BRUNO C; CARVALHO LUISA C R; ESTEVAO MONICA S; SEKERA MICHAEL H; MARQUES M MANUEL B,期刊:SYNLETT, 页码:753-756 , 文章类型: Article,,卷期:2010年-5]
  • A new clomiphene metabolite, extremely useful for doping analysis, was synthesized in 19% overall yield. The approach involved a Grignard reaction via a N-acylbenzotriazole intermediate to afford a key aromatic ketone an...
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