- Catalytic Amide-Directed Palladadesilylation-Alkenylation
[作者:RAUF WAQAR; BROWN JOHN M,期刊:SYNLETT, 页码:3103-3106 , 文章类型: Article,,卷期:2009年-19]
- Palladium(II) complexes catalyse the amide-directed displacement of an aryl-Si group and its replacement by an electrophilic alkene at ambient temperature, analogous to an oxidative Heck reaction. A palladacyclic interme...
- Concise Synthesis of (2S,3R)-3-Hydroxy-2-phenylpiperidine: An Advanced Key Intermediate of Human Non-Peptide NK-1 Receptor Antagonists
[作者:HELAL BENOIT; FERREIRA FRANCK; BOTUHA CANDICE; CHEMLA FABRICE; PEREZLUNA ALEJANDRO,期刊:SYNLETT, 页码:3115-3118 , 文章类型: Article,,卷期:2009年-19]
- The rapid, high-yielding synthesis of (2S,3R)-3-hydroxy-2-phenylpiperidine, a known advanced key intermediate of some non-peptide human NK-1 receptor antagonists such as (+)-CP-99,994, (+)-CP-122,721 and (+)-LP-733,060, ...
- Catalytic Intermolecular Hydroamination of Vinyl Ethers
[作者:PAHADI NIRMAL K; TUNGE JON A,期刊:SYNLETT, 页码:3135-3138 , 文章类型: Article,,卷期:2009年-19]
- This manuscript details the development of a palladium-catalyzed hydroamination of vinyl ethers. It is proposed that palladium catalyzes the hydroamination via Bronsted base catalysis, where palladium is protonated by th...
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