- Highly dispersed clay-polyolefin nanocomposites free of compatibilizers, via the in situ polymerization of a-olefins by clay-supported catalysts.
[作者:Scott, Susannah L.;Peoples, Brian C.;Yung, Cathleen;Rojas, Rene S.;Khanna, Vikram;Sano, Hironari;Suzuki, Toru;Shimizu, Fumihiko;,期刊:Chemical Communications, 页码:4186-4188 , 文章类型: 研究论文,,卷期:2008年-35]
- In situ polymn. by certain transition metal catalysts supported on and activated by acid-treated montmorillonite produces well-dispersed clay-polyolefin nanocomposites, without requiring either org. surfactants to be pre...
- Click chemistry step growth polymerization of novel a-azide-w-alkyne monomers.
[作者:Binauld, Sandra;Damiron, Denis;Hamaide, Thierry;Pascault, Jean-Pierre;Fleury, Etienne;Drockenmuller, Eric;,期刊:Chemical Communications, 页码:4138-4140 , 文章类型: 研究论文,,卷期:2008年-35]
- A novel step growth polymn. A-B strategy based on the click chem. polyaddn. of tailor-made a-azide-w-alkyne low molar mass monomers was developed, leading to polytriazole (co)polymers with tunable structures and properti...
- Lactonizations of carboxylic acid-substituted 3-fluorodihydropyridines with electrophiles: peculiar behaviour of F+.
[作者:Rudler, Henri;Parlier, Andree;Hamon, Louis;Herson, Patrick;Daran, Jean-Claude;,期刊:Chemical Communications, 页码:4150-4152 , 文章类型: 研究论文,,卷期:2008年-35]
- Compounds (More Than One Hetero Atom)) Section Whereas for 3-fluorodihydropyridine-substituted carboxylic acids electrophiles such as HCl, iodine, bromine and peracids discriminate the double bond lacking and that bearin...
- From dioxime oxalates to dihydropyrroles and phenanthridines via iminyl radicals.
[作者:Portela-Cubillo, Fernando;Scanlan, Eoin M.;Scott, Jackie S.;Walton, John C.;,期刊:Chemical Communications, 页码:4189-4191 , 文章类型: 研究论文,,卷期:2008年-35]
- Dioxime oxalates are useful precursors for the clean generation of iminyl radicals by sensitized UV photolysis and can be adapted for serviceable prepns. of 3,4-dihydro-2H-pyrroles, e.g., I, and phenanthridines, e.g., II...
- Metal-free Michael addition initiated multicomponent oxidative cyclodehydration route to polysubstituted pyridines from 1,3-dicarbonyls.
[作者:Lieby-Muller, Frederic;Allais, Christophe;Constantieux, Thierry;Rodriguez, Jean;,期刊:Chemical Communications, 页码:4207-4209 , 文章类型: 研究论文,,卷期:2008年-35]
- A simple metal-free, step-economic and selective access to polysubstituted pyridines, e.g., I (R = H, Me), from readily available substrates is reported, involving a flexible 4 ?mol. sieves promoted Michael addn. initiat...
- Bronsted acid catalyzed regioselective aza-Ferrier reaction: a novel synthetic method for a-(N-Boc-2-pyrrolidinyl) aldehydes.
[作者:Tayama, Eiji;Otoyama, Seijun;Isaka, Wataru;,期刊:Chemical Communications, 页码:4216-4218 , 文章类型: 研究论文,,卷期:2008年-35]
- The 1,4-elimination reaction of (Z)-N-Boc-2-(4-methoxy-2-alkenyloxy)pyrrolidines, e.g., I, is shown to proceed with high (1E,3E)-stereoselectivity to afford N-Boc-2-(1,3-dienyloxy)pyrrolidines, e.g., II. The Bronsted ac...
- Catalytic properties of MIL-101.
[作者:Henschel, Antje;Gedrich, Kristina;Kraehnert, Ralph;Kaskel, Stefan;,期刊:Chemical Communications, 页码:4192-4194 , 文章类型: 研究论文,,卷期:2008年-35]
- A very high catalytic activity in the cyanosilylation reaction was obsd. for MIL-101, a chromium based metal-org. framework; moreover, MIL-101 is also a remarkably stable support for palladium in hydrogenation reactions,...
- Multiple molecular logic functions and molecular calculations facilitated by surfactant's versatility.
[作者:Qian, Junhong;Qian, Xuhong;Xu, Yufang;Zhang, Shenyi;,期刊:Chemical Communications, 页码:4141-4143 , 文章类型: 研究论文,,卷期:2008年-35]
- Two isomeric compds. 1 and 2, combining intramol. charge transfer (ICT) and photoinduced electron transfer (PET) mechanisms together, were designed and used as logic gates with configurable multiple outputs; ten differen...
- Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane.
[作者:Bae, Youn-Sang;Farha, Omar K.;Spokoyny, Alexander M.;Mirkin, Chad A.;Hupp, Joseph T.;Snurr, Randall Q.;,期刊:Chemical Communications, 页码:4135-4137 , 文章类型: 研究论文,,卷期:2008年-35]
- Sepn. of CO2-CH4 mixts. was studied in carborane-based metal-org. framework materials with and without coordinatively unsatd. metal sites. The metal-org. framework material was prepd. by reaction of Zn(NO3)2 and 1,12-dih...
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